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Car Forum / Driving, Maintenance, Tuning / Maintenance and Repair / December 2007

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Fuel cell vehicles

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Don Stauffer in Minnesota - 06 Dec 2007 14:58 GMT
Our local paper ran an article about a new Honda FC vehicle in the
automotive section today.  The article waxed elequently about how the
emission is only water.  Of course, like most of these articles, it
neglects to consider emissions from MAKING the hydrogen.  Unless the
unlikely event happens where someone discovers a source of unreacted
hydrogen on earth, we have to MANUFACTURE hydrogen. If we use
electrolysis, the power plants that make the fuel likely run off of
fossil fuel. Or, the hydrogen is generated from petroleum or natural
gas, and the carbon stripped off has to go somewhere.

Also not said is if we have a good source of hydrogen we do not NEED
fuel cells.  The current gasoline or diesel engines can be adapted to
run on hydrogen. Yeah, nitrogen oxides can be a problem but these can
be reduced by the same mechanism we do it in current engines (EGR).
Scott Dorsey - 06 Dec 2007 16:23 GMT
>Also not said is if we have a good source of hydrogen we do not NEED
>fuel cells.  The current gasoline or diesel engines can be adapted to
>run on hydrogen. Yeah, nitrogen oxides can be a problem but these can
>be reduced by the same mechanism we do it in current engines (EGR).

Ideally, what we want in the short term is a fuel cell that can be
operated off of propane or gasoline without being poisoned.  Folks are
working on that.

The efficiency of the internal combustion engine is kind of poor, and
it is worse in automobile applications where the engine is throttled down
most of the time.

A fuel cell combined with an electric motor gives you high peak power,
and good efficiency at low power as well.  This means less fuel used and
therefore lower emissions.

In the long term, hydrogen distribution may turn out to be a good idea
but it's a difficult problem to solve, and there's already so much gasoline
distribution infrastructure that it's hard to replace.
--scott
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"C'est un Nagra.  C'est suisse, et tres, tres precis."

Noozer - 06 Dec 2007 22:51 GMT
> Our local paper ran an article about a new Honda FC vehicle in the
> automotive section today.  The article waxed elequently about how the
[quoted text clipped - 10 lines]
> run on hydrogen. Yeah, nitrogen oxides can be a problem but these can
> be reduced by the same mechanism we do it in current engines (EGR).

BUT, if the hydrogen is generated in only a few locations, it makes it a LOT
easier to scrub the emissions and much simpler to implement new technology.
Frank - 07 Dec 2007 12:54 GMT
> Our local paper ran an article about a new Honda FC vehicle in the
> automotive section today.  The article waxed elequently about how the
[quoted text clipped - 10 lines]
> run on hydrogen. Yeah, nitrogen oxides can be a problem but these can
> be reduced by the same mechanism we do it in current engines (EGR).

Also the minor technical problem of fueling the car and carrying tanks
with less than the thousands of pounds pressure needed.

George Olah, Nobel prize winning chemist,is touting methanol for fuel
cells. Methanol is readily available from coal or natural gas.

Commercial fuel cells are probably not going to be available for at
least 10 years.
Don Stauffer in Minnesota - 07 Dec 2007 15:05 GMT
> George Olah, Nobel prize winning chemist,is touting methanol for fuel
> cells. Methanol is readily available from coal or natural gas.
>
> Commercial fuel cells are probably not going to be available for at
> least 10 years.

Yeah, but the methanol fuel cells still have the carbon disposal
problem. I believe some of them do emit CO2.  So, it does not
eliminate greenhouse gases.  Also, making methanol requires a lot of
energy. I have been looking for figures on that, but I assume it would
be similar to ethanol production, and that process barely breaks even.
It takes almost as much energy to make ethanol than what you get
back.  Depends on the process, some are more efficient than others.
Burning biomass for fuel helps reduce petroleum consumption.
John S. - 07 Dec 2007 14:21 GMT
On Dec 6, 9:58 am, Don Stauffer in Minnesota <stauf...@usfamily.net>
wrote:
> Our local paper ran an article about a new Honda FC vehicle in the
> automotive section today.  The article waxed elequently about how the
[quoted text clipped - 10 lines]
> run on hydrogen. Yeah, nitrogen oxides can be a problem but these can
> be reduced by the same mechanism we do it in current engines (EGR).

There are significant indirect costs in producing any energy source.
Crude oil has to be pumped, transported great distances, refined and
transported again before an automobile can consume it.  Hydrocarbon
energy figures heavily into converting crude oil in the ground into
gasoline in the tank.
Don Stauffer in Minnesota - 07 Dec 2007 15:06 GMT
> There are significant indirect costs in producing any energy source.
> Crude oil has to be pumped, transported great distances, refined and
> transported again before an automobile can consume it.  Hydrocarbon
> energy figures heavily into converting crude oil in the ground into
> gasoline in the tank.

True, but you still get out a substantial fraction of the original
energy, while you get a lot less with ethanol.  And with hydrogen
production, you cannot even break even!
John S. - 07 Dec 2007 16:27 GMT
On Dec 7, 10:06 am, Don Stauffer in Minnesota <stauf...@usfamily.net>
wrote:

> > There are significant indirect costs in producing any energy source.
> > Crude oil has to be pumped, transported great distances, refined and
[quoted text clipped - 5 lines]
> energy, while you get a lot less with ethanol.  And with hydrogen
> production, you cannot even break even!

I would like to see the details for a break-even analysis for not only
for various sources of hydrogen but crude oil.  There are a lot  of
generalities being passed around  but not a whole lot of specifics.
Scott Dorsey - 07 Dec 2007 15:40 GMT
>On Dec 6, 9:58 am, Don Stauffer in Minnesota <stauf...@usfamily.net>
>wrote:
[quoted text clipped - 9 lines]
>energy figures heavily into converting crude oil in the ground into
>gasoline in the tank.

The problem is that we've had well over a century of development in
doing it with petroleum, and so the processes and procedures are pretty
well-known and stable.

This wasn't always the case... used to be kerosene lamps had a bad
reputation for exploding before they figured out how to get all of the
light gasoline and naptha fractions out of it.  But by 1890 or so, it
was safe and reliable.

Where we are with hydrogen development and distribution is about where
we were with petroleum around 1905, except that we're putting a lot less
money into development than we were putting into petroleum in 1905.
--scott
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"C'est un Nagra.  C'est suisse, et tres, tres precis."

John S. - 07 Dec 2007 16:32 GMT
> >On Dec 6, 9:58 am, Don Stauffer in Minnesota <stauf...@usfamily.net>
> >wrote:
[quoted text clipped - 13 lines]
> doing it with petroleum, and so the processes and procedures are pretty
> well-known and stable.

The point is not whether the processes for delivering one energy form
or another are stable or not, although those certainly are important
issues.  The point is that to take crude oil from the ground and
transform it intop gasoline inb the tank requires significant  amounts
of energy usually in the form of other hydrocaron produucts to be
consumed along the way.  As it is with electricity, hydrogen,
vegetable  oil, etc.

The only free lunches are those where someone else pays the tab.

> This wasn't always the case... used to be kerosene lamps had a bad
> reputation for exploding before they figured out how to get all of the
[quoted text clipped - 7 lines]
> --
> "C'est un Nagra.  C'est suisse, et tres, tres precis."
Scott Dorsey - 08 Dec 2007 00:22 GMT
>The point is not whether the processes for delivering one energy form
>or another are stable or not, although those certainly are important
[quoted text clipped - 3 lines]
>consumed along the way.  As it is with electricity, hydrogen,
>vegetable  oil, etc.

Oh, absolutely.  But as long as we have plenty of crude oil to do it
with, it doesn't matter.

The problem comes when we don't have available crude oil.  Most
"alternative energy systems" are not energy sources, but energy
distribution systems.

Hydrogen, for instance, is an energy distribution system.  You take
energy, make electricity, make hydrogen, pipe it around, and burn it
or use it in fuel cells to get motive power or more electricity.
Efficiency is pretty good.  But you need to get the energy in the
first place.

>The only free lunches are those where someone else pays the tab.

Yes, that's the marvelous thing about petroleum.  The tab was paid
with sunlight, millions of years ago.
--scott

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"C'est un Nagra.  C'est suisse, et tres, tres precis."

Don Stauffer in Minnesota - 08 Dec 2007 16:43 GMT
> The point is not whether the processes for delivering one energy form
> or another are stable or not, although those certainly are important
[quoted text clipped - 5 lines]
>
> The only free lunches are those where someone else pays the tab.

But at least petroleum products still yield a net amount of energy.
Hydrogen by electrolysis does not.  I don't know about the yield on
other methods of making hydrogen- would like to see the numbers.  For
biofuels the studies I have read does show a net gain (i.e., biofuels
ARE a SOURCE of energy) but not as much as petroleum.

Of course, in our modern world we also need to consider the
environmental consequences of various strategies to obtain energy.
John S. - 08 Dec 2007 18:49 GMT
On Dec 8, 11:43 am, Don Stauffer in Minnesota <stauf...@usfamily.net>
wrote:

> > The point is not whether the processes for delivering one energy form
> > or another are stable or not, although those certainly are important
[quoted text clipped - 14 lines]
> Of course, in our modern world we also need to consider the
> environmental consequences of various strategies to obtain energy.

What exactly is a net amount of energy and how is it measured.
Don Bruder - 08 Dec 2007 19:12 GMT
In article
<30426d83-8b3f-44de-be37-fe777920f35a@d21g2000prf.googlegroups.com>,

> On Dec 8, 11:43 am, Don Stauffer in Minnesota <stauf...@usfamily.net>
> wrote:
[quoted text clipped - 19 lines]
>
> What exactly is a net amount of energy and how is it measured.

What it is:

The amount of energy available from something after taking into account
all energy put into the making of the something. Using "pulled out of
thin air" numbers for purposes of illustration, if you can get 10 units
of energy out of a gallon of gas, and it only takes 4 units of energy to
put that gallon of gas in your tank, then gas has a "net energy" of 6
units. On the other hand, if it actually takes 14 units of energy to
pump, refine, transport, etc that gallon of gas into your tank, then
gasoline has a net energy of negative 4 - It takes more energy to put it
in your tank than what you get out of it when you use it to power the
car.

How it's measured is under debate, and pretty darn complex, when you
start thinking about it - Do you count the energy required to drill the
hole that the crude oil is pumped out of? The energy required to make
the drill in the first place? How about the energy to get it from the
hole to the refinery? Obviously, you have to count the energy used in
the actual refining process, but what about the energy used to make the
hardware (from "dig the ore out of the ground", to "build the refinery")
required to do the refining? What about transport from the refinery to
the gas station? For that matter, what about the transportation
mechanism? Do you count the fuel that gets burned to move it? The energy
(Again, from digging the ore out of the ground, to making the parts and
assembling them? And what about the factory (or factories) where this
"making" takes place? The making of the tools and materials that put the
factory together?) used in making the transport mechanism? How about the
transfer from the gas station's tank into your car? Or the energy
required to make the tools to make the materials to make the parts to
build the factory to make the pumps that transfer the gas from the
station's tanks to your car's tank? (And lets don't even get started on
the energy required to make the tools/factory/etc to make the tank, or
the energy used in getting it to the gas station to begin with, or the
energy involved in the raw materials/tools/factory/etc to build the
backhoe that burned energy digging the hole to bury the tank... You get
the idea, right?)

Like I said, pretty darn complex...

Too complex for *ME* to keep track of it all, that's for sure...

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Don Bruder - dakidd@sonic.net - If your "From:" address isn't on my whitelist,
or the subject of the message doesn't contain the exact text "PopperAndShadow"
somewhere, any message sent to this address will go in the garbage without my
ever knowing it arrived. Sorry... <http://www.sonic.net/~dakidd> for more info

John S. - 08 Dec 2007 19:24 GMT
> In article
> <30426d83-8b3f-44de-be37-fe777920f...@d21g2000prf.googlegroups.com>,
[quoted text clipped - 71 lines]
>
> - Show quoted text -

My point exactly.  The earlier poster was throwing simple one sentence
justifications that didn't make much sense.
clifto - 08 Dec 2007 20:08 GMT
> How it's measured is under debate, and pretty darn complex, when you
> start thinking about it - Do you count the energy required to drill the
[quoted text clipped - 23 lines]
>
> Too complex for *ME* to keep track of it all, that's for sure...

You forgot to add in the amount of energy you spent on estimating the energy.

Signature

Dec. 6 (Bloomberg) -- Government officials and activists flying to Bali,
Indonesia, for the United Nations meeting on climate change will cause
as much pollution as 20,000 cars in a year.

Don Bruder - 08 Dec 2007 20:45 GMT
> > How it's measured is under debate, and pretty darn complex, when you
> > start thinking about it - Do you count the energy required to drill the
[quoted text clipped - 25 lines]
>
> You forgot to add in the amount of energy you spent on estimating the energy.

Like I said, too complex for me to keep track of it all! :)

Signature

Don Bruder - dakidd@sonic.net - If your "From:" address isn't on my whitelist,
or the subject of the message doesn't contain the exact text "PopperAndShadow"
somewhere, any message sent to this address will go in the garbage without my
ever knowing it arrived. Sorry... <http://www.sonic.net/~dakidd> for more info

clifto - 07 Dec 2007 21:14 GMT
> Where we are with hydrogen development and distribution is about where
> we were with petroleum around 1905, except that we're putting a lot less
> money into development than we were putting into petroleum in 1905.

You can give the money to R&D, or you can give dividends.

Signature

Dec. 6 (Bloomberg) -- Government officials and activists flying to Bali,
Indonesia, for the United Nations meeting on climate change will cause
as much pollution as 20,000 cars in a year.

 
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