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Car Forum / Driving, Maintenance, Tuning / Maintenance and Repair / February 2005

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Coolant Voltage Potential

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frank-in-toronto - 27 Feb 2005 02:24 GMT
I just changed my heater core on my 87 chev caprice.  not too hard.

but what i saw i a paper with the new core surprised me.  it said
that if there was more than .3 volt dc between the coolant
and the negative, my aluminum heater core or rad would
get "eaten" up in no time.  they mention "days"!!!

so i checked and i had .2 before the change.  i didn't
check after, but i will.

my question: is this true? and is .3 the dividing point
between "heater core will die" and "it will last forever"?
or is lower better and i should work on the ground?
thanks...thehick
« Paul » - 27 Feb 2005 02:48 GMT
> I just changed my heater core on my 87 chev caprice.  not too hard.
>
[quoted text clipped - 10 lines]
> or is lower better and i should work on the ground?
> thanks...thehick

There is no dividing point.
Zero would be ideal, however that is impossible (for normal humans).
IMO, you should _always_ replace an aluminum core with a copper core.
A copper core will not corrode.  If you check an electromotive series
metals chart you will see why.
Adding lots of corrosion inhibitors will help.
frank-in-toronto - 27 Feb 2005 03:04 GMT
>> I just changed my heater core on my 87 chev caprice.  not too hard.
>>
[quoted text clipped - 17 lines]
>metals chart you will see why.
>Adding lots of corrosion inhibitors will help.
i'm not really sure it's aluminum and since it's inside now,
i'm not gonna check.  but one suggestion i read was to drop some
old copper pennys in the rad.  what about just some
good quality copper wire instead? or would this not
be the point?  i could try adding a wire also to
improve the grounding of the core.  as is clear, i really
don't understand what's happening.
thanks for any further help...thehick
« Paul » - 27 Feb 2005 04:17 GMT
> >> I just changed my heater core on my 87 chev caprice.  not too hard.
> >>
[quoted text clipped - 17 lines]
> >metals chart you will see why.
> >Adding lots of corrosion inhibitors will help.

> i'm not really sure it's aluminum and since it's inside now,
> i'm not gonna check.  but one suggestion i read was to drop some
[quoted text clipped - 4 lines]
> don't understand what's happening.
> thanks for any further help...thehick

Aluminum is silvery in color and copper is reddish.  If your heater
core was silvery, then it was aluminum.
Adding copper to the system will not help.  The parts themselves
must be made of copper.  Adding a lot of pure Mg _might_ help if you
can do it so that the Mg does not ever touch the Al directly.
On the other hand, the system will end up with a bunch of MgO sludge.
Adding a grounding wire to the aluminum part should accelerate
the dissolution of the aluminum part and save the iron parts.

The higher minus voltage metals protect the less minus voltage
metals by giving them an electron and then combining with
negative valence oxygen.  You can see why gold does not corrode.

Magnesium        -2.34 volts
Aluminum         -1.67
Zinc             -0.76
Iron             -0.44
Lead             -0.13
Copper           +0.34
Silver           +0.80
Gold             +1.42
The Rat - 27 Feb 2005 04:25 GMT
>>Adding lots of corrosion inhibitors will help.
>
[quoted text clipped - 5 lines]
> understand what's happening.
> thanks for any further help...thehick

The aluminum and other non-aluminum metals (dissimilar metals) in the
engine together with the coolant (electrolyte) make a battery.  That is
where the voltage comes from. That is why you want to change the coolant
at regular, recommended intervals - to keep the corrosion inhibitors up to
snuff.  Minerals in the coolant also add to the problem, another reason to
avoid typical tap water in the coolant.
frank-in-toronto - 27 Feb 2005 12:57 GMT
>The aluminum and other non-aluminum metals (dissimilar metals) in the
>engine together with the coolant (electrolyte) make a battery.  That is
>where the voltage comes from. That is why you want to change the coolant
>at regular, recommended intervals - to keep the corrosion inhibitors up to
>snuff.  Minerals in the coolant also add to the problem, another reason to
>avoid typical tap water in the coolant.

and << paul >> wrote:
> Adding a grounding wire to the aluminum part should
>accelerate the dissolution of the aluminum part and
> save the iron parts.

OK.  this is very interesting to me.  brand new also.  i have just
a little bit more questions.  if adding a ground wire to the
core will wreck it sooner, why does it use a ground clamp
at the bottom and a screw on ground clamp with
grounding wire at the top?

or am i building this up a little too much? if the antifreeze
is good and i used distilled water (which i didn't), i'd expect
nothing bad to happen any time soon.   after all, you don't
hear about everybody's heater core leaking.  unless the
car is more than 10 years old.
...thehick
« Paul » - 27 Feb 2005 16:22 GMT
> >The aluminum and other non-aluminum metals (dissimilar metals) in the
> >engine together with the coolant (electrolyte) make a battery.  That is
[quoted text clipped - 20 lines]
> car is more than 10 years old.
> ...thehick

The ground is for elimination of RFI.  If you keep the corrosion
inhibitors and antifreeze in good shape it should not matter.
It should last for several years.
Use ONLY genuine distilled water.
lugnut - 27 Feb 2005 14:42 GMT
>>>Adding lots of corrosion inhibitors will help.
>>
[quoted text clipped - 12 lines]
>snuff.  Minerals in the coolant also add to the problem, another reason to
>avoid typical tap water in the coolant.

So that's why I see these huge tanks of distilled water at
all these repair shops!!!!???  If the grounds are as they
should be and, you properly maintain tha additives in your
cooling system, there should be minimal problems.  Why the
hell sould your radiator get better water than what you
drink??  If a system is a problem even with proper
treatment, a sacrificial metal can be introduced into the
coolant to provide a "target".  I have seen Diesel systems
with a piece of magnesium suspended into the expansion tank
with a piece of mechanics wire.  I have seen these systems
with plates boted to the interior of the heat exchangers.
There are pipe plugs with the sacrificial material fastened
to them to facilitate maintenance and replacement.  None of
this should be required in a gasoline automotive system that
is mainatained in accordance with the manufcaturers
recommendations.  Diesels are a bit more demanding in this
area.
« Paul » - 27 Feb 2005 16:38 GMT
> >>>Adding lots of corrosion inhibitors will help.
> >>
[quoted text clipped - 30 lines]
> recommendations.  Diesels are a bit more demanding in this
> area.

Yes.  If you could somehow suspend enough Mg in the coolant
system and ground it outside of the system to the frame, etc.,
it should work as a sacrificial anode.  Sticking a piece of Mg
right on the other metal would only protect the area that is
touching.  Mg is THE metal to use for Aluminum but it only lasts
a few years at most.  It will turn to MgO and clog the system,
as will passive chemical inhibitors such as X-chromate.
Flush the system periodically!
clifto - 27 Feb 2005 05:33 GMT
> IMO, you should _always_ replace an aluminum core with a copper core.

Gotta be careful with that. I called on my '89 Grand Marquis and Ford
makes both an Al and a Cu core... but they're different physical fit
and one can't replace the other.
 
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