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Car Forum / Driving, Maintenance, Tuning / Maintenance and Repair / December 2005

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Damaged new CAT Converter in 3 weeks? (due to low octane gas ??)

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capnyco@yahoo.com - 22 Nov 2005 22:52 GMT
Will much appreciate an informed opinion(s) on the following:

Re: VW Jetta-91
I had a new CAT installed 3 weeks ago, but took it back last week due
to toxic smell coming inside the cabin.
My mechanic (same guy that installed it) tells me that the CAT is
damaged, and that's because I've used low octane (standard unleaded gas
!) .

The parts supplier (Northside Imports-NY) will not replace it, or just
refund half the cost, 'because' the CAT is damaged due to low octane
gas.

1) how low octane is 87 compared to 93, to make a difference?
2) Is this an acceptable claim form the auto parts seller?

the  whole thing doesn't make sense to me, but I am no expert and have
no facts to counter these allegations.

Will very much appreciate any tech. info., facts, 'rules of thumb'  to
help build an argument in this sutuation.
mst - 22 Nov 2005 23:21 GMT
> 1) how low octane is 87 compared to 93, to make a difference?
> 2) Is this an acceptable claim form the auto parts seller?
>
> the  whole thing doesn't make sense to me, but I am no expert and have
> no facts to counter these allegations.

It possible, but not probable. I'd say you have something
off causing fuel to not burn, which will ruin a cat. There
are other possibilities.

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Woody - 22 Nov 2005 23:37 GMT
Does your car specify 93 octane only? Probably not unless it is a very high
performance engine. Your mechanic is trying to cover his a.s for not fixing
the real problem in the first place. Take the car to a reputable mechanic
and have it fixed correctly as the next converter will go the same way. Bad
EGR, Bad O2 sensor, leaking injectors, etc cause too much unburned fuel to
be dumped in the exhaust and will kill the converter in short time...

> Will much appreciate an informed opinion(s) on the following:
>
[quoted text clipped - 17 lines]
> Will very much appreciate any tech. info., facts, 'rules of thumb'  to
> help build an argument in this sutuation.
Mike Romain - 22 Nov 2005 23:38 GMT
Well, my 1986 Jeep CJ7 will not run for crap on 87 octane.  It runs at
least 1/3 rich I figure because I get at least 1/3 less gas mileage than
when I use the same brand at 93 or even 92 octane.  I do 'not' have a
knock sensor in the circuit.

I go from 350 miles per tank to 250 or less, it bogs on the highway,
idles rough, blows out black crap and smells bad.

With only 800 miles of abuse like that, I would still put high test in
really quick and run a fast hard and hot couple tanks through.  The cat
might not be totally dead, just flooded out.

Mike
86/00 CJ7 Laredo, 33x9.5 BFG Muds, 'glass nose to tail in '00
88 Cherokee 235 BFG AT's
Canadian Off Road Trips Photos:  Non members can still view!
Aug./05 http://www.imagestation.com/album/index.html?id=2120343242
(More Off Road album links at bottom of the view page)

> Will much appreciate an informed opinion(s) on the following:
>
[quoted text clipped - 17 lines]
> Will very much appreciate any tech. info., facts, 'rules of thumb'  to
> help build an argument in this sutuation.
mst - 22 Nov 2005 23:51 GMT
> The cat might not be totally dead, just flooded out.

Flooded out?

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HLS@nospam.nix - 23 Nov 2005 00:01 GMT
> > The cat might not be totally dead, just flooded out.
>
> Flooded out?

Overloaded with hydrocarbons.

I doubt seriously...would be almost willing to underwrite...that the low
octane story is total
bullshit...a.s covering.
Shep - 23 Nov 2005 00:48 GMT
Agreed, low octane in itself will never kill a cat. conv.

>> On Tue, 22 Nov 2005 18:38:24 -0500 Mike Romain <romainm@sympatico.ca>
> wrote:
[quoted text clipped - 8 lines]
> octane story is total
> bullshit...a.s covering.
Mike Romain - 23 Nov 2005 00:55 GMT
> > The cat might not be totally dead, just flooded out.
>
> Flooded out?
>
> --

Too many HC's makes it smell like rotten eggs.  Do that for too long and
you can kill a cat from what I have read and heard.  The components get
'flooded out'.

Back in the carb days when you got the bad smell you could get backfires
that would come out the tailpipe as flame if the choke or float messed
up.  

If you got it fixed in reasonable time, it didn't usually mean you had
to change the cat.  The cat works best really hot, so a high or 'proper'
octane, high rpm run might just clean it out.  I would keep it in one
gear lower than normal for the speed for a couple tanks of gas.

Mike
86/00 CJ7 Laredo, 33x9.5 BFG Muds, 'glass nose to tail in '00
88 Cherokee 235 BFG AT's
Canadian Off Road Trips Photos:  Non members can still view!
Aug./05 http://www.imagestation.com/album/index.html?id=2120343242
(More Off Road album links at bottom of the view page)
Mike Walsh - 23 Nov 2005 01:58 GMT
> Too many HC's makes it smell like rotten eggs.  Do that for too long and
> you can kill a cat from what I have read and heard.  The components get
> 'flooded out'.

The rotten egg smell comes from sulphur, more specifically SO2 If I recall correctly.

> Back in the carb days when you got the bad smell you could get backfires
> that would come out the tailpipe as flame if the choke or float messed
> up.

A backfire comes out of the carburetor, which can be quite alarming if you happen to be working on the carburetor at the time.

Signature

                  Mike Walsh
           West Palm Beach, Florida, U.S.A.

HLS@nospam.nix - 23 Nov 2005 02:07 GMT
out'.

> The rotten egg smell comes from sulphur, more specifically SO2 If I recall correctly.

Not quite...the rotten egg smell comes from hydrogen sulfide (H2S),
mercaptans or disulfides.
Not chemically near SO2.

Sulfur is the root , but a reducing condition is the cause...catalytic
convertors normally
work in the oxidizing mode, but when overloaded with hydrocarbons, the
reduced stinky
gases (H2S) may be formed.

SO2 is a very acrid gas, reminiscent of freshly struck matches. Smells
nothing like rotten eggs.
Mike Romain - 23 Nov 2005 03:14 GMT
> > Too many HC's makes it smell like rotten eggs.  Do that for too long and
> > you can kill a cat from what I have read and heard.  The components get
> > 'flooded out'.
>
> The rotten egg smell comes from sulphur, more specifically SO2 If I recall correctly.

That is 'brimstone' smell I think, the rotted egg smell is more.

> > Back in the carb days when you got the bad smell you could get backfires
> > that would come out the tailpipe as flame if the choke or float messed
> > up.
>
> A backfire comes out of the carburetor, which can be quite alarming if you happen to be working on the carburetor at the time.

A backfire is firing on the wrong side of a valve and can happen on
either the intake or exhaust valve as far as I have seen over the
years.  

Mike
86/00 CJ7 Laredo, 33x9.5 BFG Muds, 'glass nose to tail in '00
88 Cherokee 235 BFG AT's
Canadian Off Road Trips Photos:  Non members can still view!
Aug./05 http://www.imagestation.com/album/index.html?id=2120343242
(More Off Road album links at bottom of the view page)
sdlomi2 - 23 Nov 2005 11:03 GMT
>> > The cat might not be totally dead, just flooded out.
>>
[quoted text clipped - 16 lines]
>
> Mike
   Why not try Mike's suggestion--sounds logical plus it seems you have
nothing to lose at this point.  But also try to find what *upstream*
component(s) is causing the cat problem.  Luck, s
Al Bundy - 23 Nov 2005 23:05 GMT
Hey, how long did his first converter last on the same gas he was
probably using? If he used 87 all along for 130,000 miles or something
and now needed a converter, then octane was not the culprit on the new
converter.
Alex Rodriguez - 01 Dec 2005 19:58 GMT
>Will much appreciate an informed opinion(s) on the following:
>Re: VW Jetta-91
[quoted text clipped - 12 lines]
>Will very much appreciate any tech. info., facts, 'rules of thumb'  to
>help build an argument in this sutuation.

Something fishy going on here.  Low octane by itself will not ruin an catalytic
convertor.  
------------
Alex
 
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