Home | Contact Us | FAQ | Search & Site Map | Link to Us
Sign In | Join | Other 45 Sites in Network
HomeAnnouncements
Discussion Groups
By Brand
BMWChevroletDodgeFordGMHondaLexusMercedes-BenzNissanPeugeotToyotaVolkswagenOther Brands
By Topic
4x4 CarsRVsDrivingMaintenance & RepairCar AudioCollectible Cars
Country Specific
Australian ForumsUK Forums
ArticlesAuto InsuranceBuyingCars & TechnologyMaintenanceMiscellaneousSafety
DMV Resources
Related Topics
MotorcyclesBoatsMore Topics ...

Car Forum / Driving, Maintenance, Tuning / Maintenance and Repair / April 2006

Tip: Looking for answers? Try searching our database.

Is it possible to use a 10 to 15% mix of methanol in 1997 Volvos without any problems?

Thread view: 
Enable EMail Alerts  Start New Thread
Thread rating: 
justobservant@hotmail.com - 22 Apr 2006 23:28 GMT
Hello,

I just found out that a local fuelling station sells methanol. Is it
possible to use a 10 to 15% mix of methanol in 1997 850 Volvos without
any problems to the fuel systems?

I had hoped that ethanol would be sold at my local fuelling station
(along with the biodiesel they already sell); as ethanol would be much
less likely to dmamge fuel systems than methanol.

With such high-gas prices, is 2.5 gallons (per fill-up) of methanol
economical? I read that it is best to add ethanol/methanol before
filling-up with regular 87 octance gasoline in order to assure the
beast mixing of different fuels.

Thank-you
Shep - 23 Apr 2006 01:22 GMT
10% is being introduced as we speak, almost nationwide.
> Hello,
>
[quoted text clipped - 12 lines]
>
> Thank-you
aarcuda69062 - 23 Apr 2006 01:45 GMT
> 10% is being introduced as we speak, almost nationwide.

Ethanol, not Methanol.
Shep - 23 Apr 2006 15:57 GMT
Neil, I was " asleep at the helm" on that one, alcohol funny car guys should
kick in here on the issues with methanol.

>> 10% is being introduced as we speak, almost nationwide.
>
> Ethanol, not Methanol.
aarcuda69062 - 23 Apr 2006 16:29 GMT
> Neil, I was " asleep at the helm" on that one,

No problem...

> alcohol funny car guys should
> kick in here on the issues with methanol.

As luck would have it, the only guy I know CC'd nitro fuel
dragsters 8-(
aarcuda69062 - 23 Apr 2006 01:42 GMT
In article
<1145744890.116155.187240@i39g2000cwa.googlegroups.com>,

> Hello,
>
> I just found out that a local fuelling station sells methanol. Is it
> possible to use a 10 to 15% mix of methanol in 1997 850 Volvos without
> any problems to the fuel systems?

I would have to emphatically say no unless your owners manual
specifically states that XX% methanol can be used.
Methanol is nasty stuff, not something that one should casually
mess around with.

> I had hoped that ethanol would be sold at my local fuelling station

Why?

> (along with the biodiesel they already sell); as ethanol would be much
> less likely to dmamge fuel systems than methanol.

It is, but only up to 10% typically.

> With such high-gas prices, is 2.5 gallons (per fill-up) of methanol
> economical?

Do you realize that methanol is highly toxic?

> I read that it is best to add ethanol/methanol before
> filling-up with regular 87 octance gasoline in order to assure the
> beast mixing of different fuels.

You may want to ponder why 'to go' coffee cups have lids on them.
zencraps@comcast.net - 23 Apr 2006 01:48 GMT
Here in Portland, Oregon all the gas stations sell a 10% of alcohol
with their gas during the cooler months.

Supposed to combat air pollution.

No real problems noted with it.
aarcuda69062 - 23 Apr 2006 02:22 GMT
In article
<1145753328.577376.66840@v46g2000cwv.googlegroups.com>,

> Here in Portland, Oregon all the gas stations sell a 10% of alcohol
> with their gas during the cooler months.

It's not methanol. (there is a BIG difference)

> Supposed to combat air pollution.

Supposed to...

> No real problems noted with it.

Your considerations aren't broad enough.
fiveiron@webtv.net - 23 Apr 2006 02:41 GMT
wouldn't that be some sh.t now, if us texans had to use in excess of 10%

ethanol in our gasoline - just because a bunch of ignoramuses - didn't
have, didn't

want to, or had nothing else better to do than let it happen?

I like the option or even the necessity of using 10% ethanol in gas, if
mtbe is as

hostile to the environment - as we have been led to believe.

gets sillier by the minute.:--)

mho
vƒe
=AB Paul =BB - 23 Apr 2006 04:54 GMT
> wouldn't that be some sh.t now, if us texans had to use in excess of 10%
> ethanol in our gasoline - just because a bunch of ignoramuses - didn't
[quoted text clipped - 3 lines]
> mtbe is as hostile to the environment - as we have been led to believe.
> gets sillier by the minute.:--)

Why?
=AB Paul =BB - 23 Apr 2006 02:51 GMT
> Hello,
>
[quoted text clipped - 12 lines]
>
> Thank-you

Meth is nasty, dangerous stuff.  It will eat the aluminum out of your engine.  It
takes special equipment to use it.  Stay away from it.  It is difficult to wash
off and it is skin adsorbent.  Even the exhaust vapors are dangerous unless
catalyzed.
Michael Pardee - 23 Apr 2006 16:01 GMT
"« Paul »" <"=?x-user-defined?Q?=AB?= Paul
=?x-user-defined?Q?=BB?="@houston.rr.com> wrote in message
news:444ADDD3.C370F02A@houston.rr.com...

>> Hello,
>>
[quoted text clipped - 20 lines]
> unless
> catalyzed.

I didn't know that about aluminum, but wikipedia concurs:
"One of the drawbacks of methanol as a fuel is its corrosivity to some
metals, including aluminium. Methanol, although only a weak acid, attacks
the oxide coating that normally protects the aluminium from corrosion:
 6CH3OH + 2Al ? 2Al3+ + 6CH3O- + 3H2
The resulting methoxide salts are soluble in methanol, so the corrosion
continues until the metal is eaten away."

http://en.wikipedia.org/wiki/Methanol

Considering your cylinder head is aluminum and it is exposed to raw fuel,
methanol sounds like an exceptionally bad thing to put in your tank.

Mike
Michael Pardee - 23 Apr 2006 16:14 GMT
> I didn't know that about aluminum, but wikipedia concurs:
> "One of the drawbacks of methanol as a fuel is its corrosivity to some
> metals, including aluminium. Methanol, although only a weak acid, attacks
> the oxide coating that normally protects the aluminium from corrosion:
>  6CH3OH + 2Al ? 2Al3+ + 6CH3O- + 3H2

Hmm... the punctuation didn't survive the copy and paste! Maybe this is
Martian chemistry notation.

Mike
John S. - 23 Apr 2006 02:53 GMT
> Hello,
>
[quoted text clipped - 12 lines]
>
> Thank-you

That would be an excellent question to pose to your local Volvo dealer.
John Horner - 23 Apr 2006 06:26 GMT
>>Hello,
>>
[quoted text clipped - 14 lines]
>
> That would be an excellent question to pose to your local Volvo dealer.

Hah, the chances that anyone at your local dealer would really know what
the technical issues are an how well a '97 Volvo is or is not suited for
dealing with methonal is almost zero.   Sure you will find people there
who will answer the question, but what makes you think the answer will
be well founded ?????

JOhn
HLS@nospam.nix - 23 Apr 2006 13:42 GMT
"John Horner" <jthorner@yahoo.com> wrote in message news:JdE2g.350> Hah, the
chances that anyone at your local dealer would really know what
> the technical issues are an how well a '97 Volvo is or is not suited for
> dealing with methonal is almost zero.   Sure you will find people there
> who will answer the question, but what makes you think the answer will
> be well founded ?????
>
> JOhn

Well said...you might get an answer but it is likely to just be an opinion.

I don't think it is too wise to use methanol in this application, but it has
little to do with the toxicity:

- Methanol will mix with gasoline only if it is rather anhydrous.  A little
water
and the mixture falls apart.   Ethanol is much better, isopropanol is better
still,
etc.

- Methanol  will attack some metals with the formation of metallic
methoxides.
  The higher alcohols do it too, but apparently less readily.

Get accustomed to paying higher prices for gasoline.....or driving
less....or getting
a more economical ride.  While there is no physical petroleum shortage at
the
moment, the prices are being forced up by speculation in the market.

There is a concentrational shortage of petroleum products, and in the
nearing
future, I believe the shortages will become physically real.
John S. - 23 Apr 2006 14:10 GMT
> >>Hello,
> >>
[quoted text clipped - 20 lines]
> who will answer the question, but what makes you think the answer will
> be well founded ?????

I think the chances of his getting an informed and accurate answer to a
technical question about the use of modified fuels in an older car are
far far better at a dealer than they are on a news group.
Lawrence Glickman - 23 Apr 2006 14:17 GMT
>> >>Hello,
>> >>
[quoted text clipped - 20 lines]
>> who will answer the question, but what makes you think the answer will
>> be well founded ?????

==============================================================
>I think the chances of his getting an informed and accurate answer to a
>technical question about the use of modified fuels in an older car are
>far far better at a dealer than they are on a news group.

"Used Car Salesman" is a derogatory epithet when used in the USA.

I would rather google newsgroups.

Lg
Michael Pardee - 23 Apr 2006 15:56 GMT
> I think the chances of his getting an informed and accurate answer to a
> technical question about the use of modified fuels in an older car are
> far far better at a dealer than they are on a news group.

I disagree, especially in this forum where there are some top-level gurus.
Few if any dealers have the expertise and experience available here. You
just have to be able to vet information.

Mike
John S. - 24 Apr 2006 01:45 GMT
> > I think the chances of his getting an informed and accurate answer to a
> > technical question about the use of modified fuels in an older car are
[quoted text clipped - 5 lines]
>
> Mike

Self-important internet "gurus" are not in my experience reliable
sources of information. They are usually good for more than one
partially informed opinion however.  The dealer technicians and
corporate support staff are going to be a far more reliable source of
information.
Michael Pardee - 24 Apr 2006 02:24 GMT
>> > I think the chances of his getting an informed and accurate answer to a
>> > technical question about the use of modified fuels in an older car are
[quoted text clipped - 12 lines]
> corporate support staff are going to be a far more reliable source of
> information.

It is we who validate the gurus, not they who validate themselves (as
dealers do, after all... money to invest is the main qualification for that
rating.) Because of the cross-posting I'm not sure which forum brings you
here, but alt.autos.volvo has a couple of professionals and at least one
very talented amateur who rarely set a foot wrong. I've been following the
group since we got our Volvo about 16 years ago and I trust them more than I
did my dealer... when we still had one in the state.

I am a dedicated DIYer who has resorted to dealers only three times in as
many decades and regretted it once, but at least three of the Volvo gurus
are several notches above me by any sane reckoning. One of them - a pro -
has posted in this thread.

My partner, who used to work at a Porsche dealership in Phoenix, warned me
that service writers are usually the least experienced mechanics at a shop.
The experienced ones are busy with cars, not with customers.

But to each their own - believe whom you will.

Mike

"The main, if not the sole, purpose of education is to be able to detect
when a man is talking rot." John Alexander Smith (1914), as reported by
Harold Macmillan
Mike F - 27 Apr 2006 15:12 GMT
> It is we who validate the gurus, not they who validate themselves (as
> dealers do, after all... money to invest is the main qualification for that
[quoted text clipped - 20 lines]
> when a man is talking rot." John Alexander Smith (1914), as reported by
> Harold Macmillan

And while I also would trust something I read on the internet,
especially from someone who has a history of knowing what they're
talking about, over some dealer service advisor whose function is to
sell, sell, sell, a source better than either is the owners manual.  The
one for my '98 V70 (which is almost identical to the OP's '97 850 from a
fuel system standpoint) states:

"Do not use gasolines containing methanol (methyl alcohol, wood
alcohol).  The practice can result in vehicle performance deterioration
and can damage critical parts in the fuel system.  Such damage may not
be covered under the New Vehicle Limited Warranty."

That seems pretty conclusive.

Signature

Mike F.
Thornhill (near Toronto), Ont.

Replace tt with t (twice!) and remove parentheses to email me directly.
(But I check the newsgroup more often than this email address.)

Aawara Chowdhury - 28 Apr 2006 02:04 GMT
>> It is we who validate the gurus, not they who validate themselves (as
>> dealers do, after all... money to invest is the main qualification for that
[quoted text clipped - 34 lines]
>
> That seems pretty conclusive.

In general, Mike F, I agree with you.  However, the owner's manual (esp.
well-pass warranty) may not be the best source of information either.
For example, I use regular (87 octane) in my Volvo 850 - which is normally
aspirated.

Neither the manual, nor the dealer recommend using 87 octane fuel.  However,
others on this group - such as Dr. Stephen Henning have used it with no
ill effects on several Volvos including one similar to that which I drive.

So, I guess, whatever the source of information, one has to be able to
whet it.

AC
Signature

Email: echo 142322093203359315271794620168064975321554275890186P | dc

lucasea@sbcglobal.net - 28 Apr 2006 02:18 GMT
> And while I also would trust something I read on the internet,
> especially from someone who has a history of knowing what they're
> talking about, over some dealer service advisor whose function is to
> sell, sell, sell, a source better than either is the owners manual.

I generally agree with you.  However, you have to understand that the car
company also has a vested interest in saying what they do--it's a form of
CYA.  Tell the owner that they can't do anything but a very narrowly defined
set of "correct use", and you've got a basis to void the warranty if
something goes wrong with the car.  I'm not saying that's true in this case,
just pointing out that the owner's manual is not exactly an objective source
of information.  For example, I frequent the Miata newsgroup, and that
owner's manual says to never, ever, ever, ever tow anything with the Miata.
There are a several people on that newsgroup that have thousands of miles of
towing trailers, without a mishap or damage to their car, and nobody there
is saying "hey, guys, I have had problems towing a trailer with the Miata."
Seems pretty clear that that part of the owner's manual is nothing but CYA.

> The
> one for my '98 V70 (which is almost identical to the OP's '97 850 from a
[quoted text clipped - 6 lines]
>
> That seems pretty conclusive.

Conclusive specifically about methanol.  Methanol and ethanol are very
different--methanol is much more hydroscopic and corrosive, and much more
polar (i.e., likely to extract rubber additives), and thus much more likely
to cause damage to an engine.  Since they specifically mentioned methanol, I
would read that to mean ethanol-containing fuels are fine.

Eric Lucas
Mike F - 28 Apr 2006 17:38 GMT
> > And while I also would trust something I read on the internet,
> > especially from someone who has a history of knowing what they're
[quoted text clipped - 32 lines]
>
> Eric Lucas

Well what you are saying is true to an extent - and I know lots of
people who tow with cars where the owners manual warns against it.  But
owners manuals are written also with a worst case scenario too, like if
you're towing a trailer with your Miata up a mountain road at high speed
on the hottest day of the year in the deserts of Arizona with the A/C on
full blast while tailgating another car so closely that airflow to the
rad is blocked.  Or perhaps it's brake related, same scenario, this time
going down the mountain, automatic transmission in Drive, riding the
brakes all the way.

However in cases like using fuel, there's really only one scenario -
using it is using it.  And in this particular owners manual, I didn't
post everything written about the fuel requirements, that was more than
a whole page.  It did allow a composition of up to 10% ethanol, as well
as allowing other additives.

Signature

Mike F.
Thornhill (near Toronto), Ont.

Replace tt with t (twice!) and remove parentheses to email me directly.
(But I check the newsgroup more often than this email address.)

HLS@nospam.nix - 23 Apr 2006 18:42 GMT
> I think the chances of his getting an informed and accurate answer to a
> technical question about the use of modified fuels in an older car are
> far far better at a dealer than they are on a news group.

You are certainly entitled to your opinion, but it is one I do not share.

Dealerships tend to be staffed by salesmen.

While some dealerships have excellent mechanics (and some don't),
few  - if any - employees at a dealership would have the basic engineering
skills to comment on this issue with any authority.

If any of them would take the time to go to Volvo engineering and pose
this question, I would be a little surprised.
John S. - 24 Apr 2006 01:53 GMT
> > I think the chances of his getting an informed and accurate answer to a
> > technical question about the use of modified fuels in an older car are
[quoted text clipped - 3 lines]
>
> Dealerships tend to be staffed by salesmen.

Well, yes dealerships do employ salespeople (men and women).  But I
don't take my car to the sales rep for repairs nor do I buy parts from
her.

> While some dealerships have excellent mechanics (and some don't),
> few  - if any - employees at a dealership would have the basic engineering
> skills to comment on this issue with any authority.

There is a far greater chance of getting an informed opinion from the
technical department in a dealer than on a news group.  Wish the news
groups were like they once were, but they are not.  They no longer
reliable sources of technical information.  Is good information
there...yes there can be, but it is usually buried.

> If any of them would take the time to go to Volvo engineering and pose
> this question, I would be a little surprised.
Don Stauffer - 24 Apr 2006 14:44 GMT
I was watching a CNN special last night on energy crunch.  They had a
segment on Brazil's ethanol push.  They claim regular gasoline (not E85)
had 25% ethanol (making it E25, I guess).
Boris Mohar - 27 Apr 2006 13:31 GMT
>I was watching a CNN special last night on energy crunch.  They had a
>segment on Brazil's ethanol push.  They claim regular gasoline (not E85)
>had 25% ethanol (making it E25, I guess).

E75

http://www.eere.energy.gov/afdc/pdfs/982531.pdf

Regards,

Boris Mohar

Got Knock? - see:
Viatrack Printed Circuit Designs (among other things) http://www.viatrack.ca

void _-void-_ in the obvious place


Aawara Chowdhury - 27 Apr 2006 14:00 GMT
>>I was watching a CNN special last night on energy crunch.  They had a
>>segment on Brazil's ethanol push.  They claim regular gasoline (not E85)
[quoted text clipped - 3 lines]
>
> http://www.eere.energy.gov/afdc/pdfs/982531.pdf

No - E75 would be 75% ethanol, 25% gasoline.  The gasoline in Brazil
has 25% ethanol, 75% gasoline.  That would be E25.

My understanding is that Brazil also leads the world in the sale of
flex-fuel vehicles, as a percentage of total vehicle sales.

AC
Signature

Email: echo 142322093203359315271794620168064975321554275890186P | dc

Steve - 24 Apr 2006 03:25 GMT
> > >>Hello,
> > >>
[quoted text clipped - 24 lines]
> technical question about the use of modified fuels in an older car are
> far far better at a dealer than they are on a news group.

The dealer has the great majority of their business from new cars.  a 9 year
old model is not goig to be their strong suit.

All the dealer will do is to say whatever volvo says anyway, therefore the
correct course is to write a email or call here:
Volvo Customer Care Center
For questions about the Volvo you currently own.

Volvo Cars of North America, LLC
Attn: Volvo Customer Care Center
7 Volvo Drive
Rockleigh, New Jersey 07647

Tel: 1-800-458-1552
Email: customercare@volvocars.com
Hours: 8:30 AM to 7:00 PM EST, M - F
John Robertson - 27 Apr 2006 03:05 GMT
I rang Volvo Australia and was told 5% max and then I am not sure as even
between brands there seems to be a difference in my Turbo if I push it .So
far I have avoided the use of Methanol but as our Prime minister has a mate
who is in to producing methanol it no doubt will be forced on us .My hose
between my tanks rotted so did my wifes both cars were brought second hand
from Sydney Australia where Methanol is common and it does rot hoses rubber
and such .

>> >>Hello,
>> >>
[quoted text clipped - 24 lines]
> technical question about the use of modified fuels in an older car are
> far far better at a dealer than they are on a news group.
athol - 27 Apr 2006 03:50 GMT
In alt.autos.volvo John Robertson <johnnr@optusnet.com.au> wrote:
> I rang Volvo Australia and was told 5% max and then I am not sure as even
> between brands there seems to be a difference in my Turbo if I push it .So
[quoted text clipped - 3 lines]
> from Sydney Australia where Methanol is common and it does rot hoses rubber
> and such .

Australia is moving towards the use of up to 10% _Ethanol_, *not* _Methanol_.

Completely different stuff.  Ethanol is the alcohol in drinks - it's not as
poisonous or carcinogenic as methanol, or as corrosive.  :-)

Signature

Athol
<http://cust.idl.com.au/athol>   Linux Registered User # 254000
The state of infrastructure in New South Wales is a disgrace.
I'm a Libran Engineer. I don't argue, I discuss.

Andrew McKenna - 28 Apr 2006 09:16 GMT
> In alt.autos.volvo John Robertson <johnnr@optusnet.com.au> wrote:
>
[quoted text clipped - 10 lines]
> Completely different stuff.  Ethanol is the alcohol in drinks - it's not as
> poisonous or carcinogenic as methanol, or as corrosive.  :-)

http://en.wikipedia.org/wiki/Ethanol_fuel

Signature

Cheers

Andrew

athol - 23 Apr 2006 06:53 GMT
In alt.autos.volvo justobservant@hotmail.com wrote:

> I just found out that a local fuelling station sells methanol. Is it
> possible to use a 10 to 15% mix of methanol in 1997 850 Volvos without
> any problems to the fuel systems?

Depends whether it's a diesel and you're making biodiesel from waste
frying oil.  If so, you'll need methanol as part of the processing, and
it'll be used at a rate of 10% of the final fuel quantity made.  If not,
methanol should not be used.

Signature

Athol
<http://cust.idl.com.au/athol>   Linux Registered User # 254000
The state of infrastructure in New South Wales is a disgrace.
I'm a Libran Engineer. I don't argue, I discuss.

Milanjot - 23 Apr 2006 10:39 GMT
Usually it is possible to use 10% metho. but is any hight
concentrations are used then the tubing in the fuel pipes needs to be
replaced to be compatible with metho
Michael Pardee - 23 Apr 2006 15:50 GMT
> Hello,
>
[quoted text clipped - 12 lines]
>
> Thank-you

When we bought our '85 (used) the dealer warned us not to put methanol
blended fuel in the tank - ethanol and MTBE were okay.

Mike
raconte@hotmail.com - 23 Apr 2006 16:11 GMT
> Hello,
>
[quoted text clipped - 12 lines]
>
> Thank-you

In addition to what's already been posted about the corrosive effects,
will you really save money?  What does 2.5 gal of methanol cost?  And
how much mileage per gallon will you lose by using methanol?  The is
not likely a real cost savings at work here, so unless you have a
reference that says otherwise, you really shouldn't do it.
HLS@nospam.nix - 23 Apr 2006 18:44 GMT
> What does 2.5 gal of methanol cost?  And
> how much mileage per gallon will you lose by using methanol?  The is
> not likely a real cost savings at work here, so unless you have a
> reference that says otherwise, you really shouldn't do it.

That is another good point.  I remember, dimly, when technical grade
methanol could be purchased in bulk for $0.40 per gallon.  Not any more.
raconte@hotmail.com - 24 Apr 2006 01:13 GMT
> > What does 2.5 gal of methanol cost?  And
> > how much mileage per gallon will you lose by using methanol?  The is
[quoted text clipped - 3 lines]
> That is another good point.  I remember, dimly, when technical grade
> methanol could be purchased in bulk for $0.40 per gallon.  Not any more.

'Couse not.  Methanol is made from petroleum.  Well, natural gas
anyway.  Now if some nation or locality has tons of natural gas and no
petroleum, and wants to make some money, they can try and get their
synthesis subsidized ...  Maybe we'll see it be cost effective.  Hey,
it works for corn producers in the US, sugar cane growers in Brazil,
and wine makers in the EU (I'm talking ethanol here).

But still, its not energy effective.  That oxygen atom in the molecule
causes the fuel to produce more water, and volatizing water, with its
high specific heat, robs the engine of power.  That's not oil company
propaganda, that's chemistry.

Everyone's trying stuff like this.  People were using used frying oil
in their disel engines.  Got for free from fast-food places ... until
they found out what it was being used for.  Then the supply dried up.
N:dlzc D:aol T:com (dlzc) - 24 Apr 2006 01:21 GMT
Dear raconte:

...
> But still, its not energy effective.  That oxygen atom in
> the molecule causes the fuel to produce more water,
> and volatizing water, with its high specific heat, robs
> the engine of power.  That's not oil company
> propaganda, that's chemistry.

Any internal combustion engine uses air/oxygen as an oxidizer,
and produces water where *hydrogen* is present in the fuel.
Alcohol has no leg either up *or* down on petroleum fuels,
because they all oxidize with oxygen and they all have hydrogen.

So is it the carbon chain that provides the most energy?

David A. Smith
Nate Nagel - 24 Apr 2006 01:49 GMT
> Dear raconte:
>
[quoted text clipped - 14 lines]
>
> David A. Smith

Alcohol has some oxygen already built into it, so you might think of it
as an already partially oxidized hydrocarbon.  (I can hear chemists
cringing as I type this)  In any case a given volume of *thanol will not
react with as much atmospheric oxygen as will a given volume of
gasoline; that is why it is less energy dense.

nate

Signature

replace "fly" with "com" to reply.
http://home.comcast.net/~njnagel

Michael Pardee - 24 Apr 2006 02:01 GMT
> Any internal combustion engine uses air/oxygen as an oxidizer, and
> produces water where *hydrogen* is present in the fuel. Alcohol has no leg
[quoted text clipped - 4 lines]
>
> David A. Smith

Both provide energy. A significant part of the problem is that methanol is
already partially oxidized, as are all alcohols. The energy content of
methanol is about 60% that of gasoline (http://tinyurl.com/f6nyl). The same
site proclaims that at the time of publication (1997) methanol fuel M-85 was
selling for the same price as gasoline in California. Your guess is as good
as mine where the price stands today, if it is available. Of course, the 40%
reduction in fuel efficiency would still apply.

Mike
HLS@nospam.nix - 24 Apr 2006 15:54 GMT
> So is it the carbon chain that provides the most energy?
>
> David A. Smith

Let's answer this one definitively.  No, the combustion of carbon
in a hydrocarbon chain doe NOT provide the most energy.  The
hydrogen combustion is the clear winner.

While alcohols may not be desirable in terms of our traditional
perceptions of energy economics, we may have to change out
perceptions.  $100 per barrel oil is a possibility if not a likelihood.

Brasil does indeed have alcohol fuel available at many stations and
ALL their regular gasoline has 25% ethanol added.  Most of their
cars have Flexifuel capacity, and can burn just about any mixture.

The factories produce both sugar and alcohol, and the energy to
do this is provided by burning the bagasse for heat.  Brasil did it
because they HAD to do something.  We might be seen as lagging
behind them, yearning for cheap petroleum to return.  (Cheap
petroleum and Vaudeville are two things we are not likely to see
again.)

I have wondered why the 'water gas' reaction has not gotten more
hype.  Carbon reacts with water at high temperatures to yield hydrogen,
carbon monoxide, and other by-products.  At least the first two
are reasonably good fuels.  And we have plenty of coal...and water.
N:dlzc D:aol T:com (dlzc) - 25 Apr 2006 01:08 GMT
Dear HLS:

...
> I have wondered why the 'water gas' reaction has not
> gotten more hype.  Carbon reacts with water at high
> temperatures to yield hydrogen, carbon monoxide,
> and other by-products.  At least the first two are
> reasonably good fuels.  And we have plenty of coal...
> and water.

Not really plenty of either.  As far as coal goes, if it isn't
destined for a power plant, then it is being shipped to Japan.
We are already using every drop of water that falls on the US
pretty close to x1 before it hits the ocean again.  Plus
siphoning it out of the ground...

David A. Smith
Michael Pardee - 25 Apr 2006 01:48 GMT
>> So is it the carbon chain that provides the most energy?
>>
[quoted text clipped - 23 lines]
> carbon monoxide, and other by-products.  At least the first two
> are reasonably good fuels.  And we have plenty of coal...and water.

The contaminants in the coal are the problem. The electric utility I work
for used to make "coal gas" and the production sites have cost us a fortune
to clean up. The heavy metals left behind made for mighty toxic waste.

Mike
N:dlzc D:aol T:com (dlzc) - 25 Apr 2006 02:03 GMT
Dear Michael Pardee:

...
>> I have wondered why the 'water gas' reaction has
>> not gotten more hype.  Carbon reacts with water
[quoted text clipped - 8 lines]
> The heavy metals left behind made for
> mighty toxic waste.

They have lots of power and heat available.  Couldn't they either
allow the water to boil off/evaporate, or simply plate the heavy
metals onto something?  Heavy metals are being removed in
municipal drinking water systems through their adsorption onto
iron...

As a side light, medical product sterilizers that use ETO have to
get rid of this gas once it has been used.  They convert it into
ethylene glycol, which they still have to dispose of as a
hazardous material... and we get cheap(er) engine coolant (I
guess).

Is it just a "regulation thing"?

David A. Smith
HLS@nospam.nix - 29 Apr 2006 03:28 GMT
"Michael Pardee" <michaeltnull@cybertrails.com> wrote in message
> The contaminants in the coal are the problem. The electric utility I work
> for used to make "coal gas" and the production sites have cost us a fortune
> to clean up. The heavy metals left behind made for mighty toxic waste.
>
> Mike

That is one thing that always comes to the top...that the cost of energy
is increasing.  Petroleum has been the king for a long time.  There is no
obvious and immediate successor to the throne.

However, in electric plants where coal is burned, the same heavy metals
are left behind in the ash.   The sulfur is still freed by the process.

Maybe your gas process is expensive, and the waste is nasty, but it is
unlikely to be any worse than the waste generated by burning the coal.

There just is no free lunch, is there?
justobservant@hotmail.com - 23 Apr 2006 23:51 GMT
> > Hello,
> >
[quoted text clipped - 18 lines]
> not likely a real cost savings at work here, so unless you have a
> reference that says otherwise, you really shouldn't do it.

Since this post was also published in the 'sci.chem' forum, is it
possible to use additives that would diminish methanol's corrosive
effects?

And would a 10 to 15% ratio of methanol to gasoline be enough to yield
fuel-economy savings simply by defraying gasoline use, yet not enough
methanol to "lessen fuel-economy" overall?
Michael Pardee - 24 Apr 2006 00:08 GMT
> Since this post was also published in the 'sci.chem' forum, is it
> possible to use additives that would diminish methanol's corrosive
[quoted text clipped - 3 lines]
> fuel-economy savings simply by defraying gasoline use, yet not enough
> methanol to "lessen fuel-economy" overall?

I suppose it could be possible, but where are we going with this? Methanol
really isn't a cheap substitute for gasoline, and any dilution of a fuel
with a less energy dense fuel will proportionately reduce the energy
available. I know that is an oversimplification, but I still don't see why
we'd want to.

I'm reminded of the acetone additive posts. Big risks, small motive to take
them.

Mike
User - 24 Apr 2006 02:01 GMT
> > Since this post was also published in the 'sci.chem' forum, is it
> > possible to use additives that would diminish methanol's corrosive
[quoted text clipped - 14 lines]
>
> Mike

The other part of the calculation is that since alcohols burn cooler
(lower heat of oxidation, lower latent heat overall) you would
theoretically be able to run more advance and utilize more power from
the gasoline fraction. However the control unit won't allow the advance
numbers you would need to neutralize the lost energy (from dilution) so
that adding oxidizers of any sort just waters down the fuel. The O2
sensor output to the control unit will maximize efficiency and reduce
emissions if the engine is running correctly. Most incomplete combustion
byproducts are cleaned in the converters. Adding O2 to the exhaust
stream just fools the O2 sensor output causing the control unit to feed
more fuel in an attempt to bring the air-fuel ratio back to calculated
lambda which is just slightly richer at 14.65:1 vs. 14.7:1.

AS far as methanol goes there was a bulletin of somekind that circulated
through the dealerships disallowing the use of methanol fuels. Among the
components affected were the fuel sock in the tank, the bellows hose on
the tank, the bracket and some of the plastics used for the in tank
pumps, the hard plastic nylon fuel lines were somewhat affected, and
most all rubber hoses were destroyed. There was no mention of engine
damage that I recall.

Bob  
Signature

The goal when driving is to miss the maximum number of objects.


Rate this thread:






 
Sign In
Join
My Latest Posts
My Monitored Threads
My Blog
My Photo Gallery
My Profile
My Homepage

Start New Thread
Enable EMail Alerts
Rate this Thread



©2008 Advenet LLC   Privacy Policy - Terms of Use
This website includes both content owned or controlled by Advenet as well as content owned or controlled by third parties.