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Car Forum / Honda Cars / June 2009

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Uncracked gas?

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Dillon Pyron - 25 Jun 2009 20:34 GMT
Okay, this was way back.  Like when we were driving an almost brand
new 84 Escort GT.  There was a gas station on I35 in Farmer's Branch
(just north of Dallas) that sold various "high premium" fuels.  One of
them as 112 octane "uncracked".  Just what does that mean?

I'm "old enough" to have put Sunoco 120 in my 427 Galaxie 500.  Um,
when I was doing the quarter, it kind of needed it.
Signature


- dillon  I am not invalid

"Jimmy, I'm sorry your girlfriend turned out
to be a cylon."
-Special Agent Tim McGee, "NCIS"

News - 25 Jun 2009 20:45 GMT
> Okay, this was way back.  Like when we were driving an almost brand
> new 84 Escort GT.  There was a gas station on I35 in Farmer's Branch
[quoted text clipped - 3 lines]
> I'm "old enough" to have put Sunoco 120 in my 427 Galaxie 500.  Um,
> when I was doing the quarter, it kind of needed it.

It was Sunoco 260.
Dillon Pyron - 29 Jun 2009 22:56 GMT
>> Okay, this was way back.  Like when we were driving an almost brand
>> new 84 Escort GT.  There was a gas station on I35 in Farmer's Branch
[quoted text clipped - 5 lines]
>
>It was Sunoco 260.

Brand name, not octane.

Signature

- dillon  I am not invalid

"Jimmy, I'm sorry your girlfriend turned out
to be a cylon."
-Special Agent Tim McGee, "NCIS"

News - 29 Jun 2009 23:28 GMT
>>> Okay, this was way back.  Like when we were driving an almost brand
>>> new 84 Escort GT.  There was a gas station on I35 in Farmer's Branch
[quoted text clipped - 7 lines]
>
> Brand name, not octane.

Sunoco 260 was 102 octane
Leftie - 25 Jun 2009 22:41 GMT
> Okay, this was way back.  Like when we were driving an almost brand
> new 84 Escort GT.  There was a gas station on I35 in Farmer's Branch
[quoted text clipped - 3 lines]
> I'm "old enough" to have put Sunoco 120 in my 427 Galaxie 500.  Um,
> when I was doing the quarter, it kind of needed it.

   Taken literally ('cracking' is the process of using catalysts to
separate the components of crude oil), it would have been crude oil.
;-) I'm assuming that it was a marketing term that refers to something else.
Enrico Fermi - 26 Jun 2009 00:50 GMT
>    Taken literally ('cracking' is the process of using catalysts to
> separate the components of crude oil), it would have been crude oil. ;-)
> I'm assuming that it was a marketing term that refers to something else.

You have been misinformed. Distillation is used to separate the components
of crude oil. One of the liquids the still produces is octane. Perhaps there
were gas stations selling pure octane in the old days. Sounds implausible
but....  The catalytic cracking unit (cat cracker) uses something called
"gas oil" as its feedstock. It's like kerosene. The gas oil is cracked and
reformed or alkylated to produce more gasoline than crude oil would contain
naturally. All fairly low-tech now. As always, the goal in refining is to
work safely and have no fatalities. Nobody want to end their shift
deceased.....
Tegger - 26 Jun 2009 01:17 GMT
> As always, the goal in refining is to work safely and
> have no fatalities.

Don't get a job with BP...

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Tegger

The Unofficial Honda/Acura FAQ
www.tegger.com/hondafaq/

Grumpy AuContraire - 26 Jun 2009 03:46 GMT
>>As always, the goal in refining is to work safely and
>>have no fatalities.
>
> Don't get a job with BP...

At least not in the Houston area.  More explosions etc that have killed
several people.

BP is not highly regarded in these heeyah pawts...

JT
Dillon Pyron - 29 Jun 2009 22:57 GMT
>>>As always, the goal in refining is to work safely and
>>>have no fatalities.
[quoted text clipped - 5 lines]
>
>BP is not highly regarded in these heeyah pawts...

Unless you're a trial lawyer (most of whom, ironically, don't go to
trial).

>JT
Signature


- dillon  I am not invalid

"Jimmy, I'm sorry your girlfriend turned out
to be a cylon."
-Special Agent Tim McGee, "NCIS"

Leftie - 26 Jun 2009 09:48 GMT
>>    Taken literally ('cracking' is the process of using catalysts to
>> separate the components of crude oil), it would have been crude oil. ;-)
[quoted text clipped - 9 lines]
> work safely and have no fatalities. Nobody want to end their shift
> deceased.....

   Amusing. I hope that wasn't a serious post. I'll have to remember to
pick up some "liquid octane" on the way home from work...

   For those who want to know:

http://en.wikipedia.org/wiki/Cracking_(chemistry)
Enrico Fermi - 26 Jun 2009 12:39 GMT
>>>    Taken literally ('cracking' is the process of using catalysts to
>>> separate the components of crude oil), it would have been crude oil. ;-)
[quoted text clipped - 16 lines]
>
> http://en.wikipedia.org/wiki/Cracking_(chemistry)

You are easily amused....Ignorance is bliss... Hope springs eternal....
Your link doesn't work. Octane IS a liquid:
Octane Definition: Any isomeric saturated hydrocarbon found in petroleum and
used as a fuel and solvent.
Tegger - 26 Jun 2009 14:03 GMT
>>>>    Taken literally ('cracking' is the process of using catalysts to
>>>> separate the components of crude oil), it would have been crude
[quoted text clipped - 21 lines]
> You are easily amused....Ignorance is bliss... Hope springs
> eternal.... Your link doesn't work.

It worked for me.

But more to the point of this thread is this page:
<http://en.wikipedia.org/wiki/Fluid_catalytic_cracking>

> Octane IS a liquid:
> Octane Definition: Any isomeric saturated hydrocarbon found in
> petroleum and used as a fuel and solvent.

For those interested...

<http://en.wikipedia.org/wiki/Octane>

<http://en.wikipedia.org/wiki/Octane_rating>

Note that "octane" and "octane rating" are NOT the same thing.

Signature

Tegger

The Unofficial Honda/Acura FAQ
www.tegger.com/hondafaq/

Grumpy AuContraire - 28 Jun 2009 04:30 GMT
>>>>   Taken literally ('cracking' is the process of using catalysts to
>>>>separate the components of crude oil), it would have been crude oil. ;-)
[quoted text clipped - 21 lines]
> Octane Definition: Any isomeric saturated hydrocarbon found in petroleum and
> used as a fuel and solvent.

A long time ago when a junior in high school, I "cracked" gasoline into
components by temperature. That said, "octane" was one of these
compounds.  But rather than me try to explain it from memory, I found this.

 "One cannot talk about the chemistry of gasoline without understanding
octane numbers. When gasoline is burned in an internal combustion engine
to CO2 and H2O, there is a tendency for many gasoline mixtures to burn
unevenly. Such nonconstant and unsmooth combustion creates a "knocking"
noise in the engine. Knocking signifies that the engine is not running
as efficiently as it could. It has been found that certain hydrocarbons
burn more smoothly than others in a gasoline mixture. In 1927 a scale
that attempted to define the "antiknock" properties of gasolines was
created. At that time, 2,2,4-trimethylpentane (commonly called
"isooctane") was the hydrocarbon that, when burned pure in an engine,
gave the best antiknock properties (caused the least knocking). This
compound was assigned the number 100, meaning it was the best
hydrocarbon to use. The worst hydrocarbon researchers could find in
gasoline (which when burned pure gave the most knocking) was n-heptane,
assigned the number 0. When isooctane and heptane were mixed, they gave
different amounts of knocking depending on their ratio: The higher the
percentage of isooctane in the mixture, the lower was the amount of
knocking. Gasoline mixtures obtained from petroleum were burned for
comparison. If a certain gasoline has the same amount of knocking as a
90 percent isooctane, 10 percent heptane (by volume) mixture, we now say
that its "octane number" is 90. Hence, the octane number of a gasoline
is the percent isooctane in an isooctane-heptane."

From:

http://www.chemistryexplained.com/Ny-Pi/Petroleum.html

I remember my mother being semi terrified of my gas boiling experiments
in the basement...

JT
Leftie - 28 Jun 2009 07:42 GMT
>>>>>   Taken literally ('cracking' is the process of using catalysts to
>>>>> separate the components of crude oil), it would have been crude
[quoted text clipped - 59 lines]
>
> JT

   I wonder why.  ;-) There is a difference between "iso-octane" ( a
compound) and "octane rating" (a measurement). I was amused at being
'corrected' by someone who didn't know the difference, and who thought
gasoline was still made by 'turn of the century before last' methods.
They don't generally add iso-octane to gasoline, they add other
compounds and use the rating system based on it, as you explained. It
also amuses me that people associate "high octane" with "highly
explosive" because it's more the opposite: kerosene would have a much
higher "octane" than gasoline, IIRC.
Enrico Fermi - 28 Jun 2009 15:47 GMT
>    I wonder why.  ;-) There is a difference between "iso-octane" ( a
> compound) and "octane rating" (a measurement). I was amused at being
[quoted text clipped - 5 lines]
> more the opposite: kerosene would have a much higher "octane" than
> gasoline, IIRC.

You have drawn conclusions from my reply that do not reflect my assertions.
The term Iso-octane is not particularly descriptive since there are 18
isomers of octane. I was referring to Normal Octane (n-octane) which is just
basic octane liquid. Iso-octane can be one or all of 17 isomers:
    2-Methylheptane
    3-Methylheptane
    4-Methylheptane
    3-Ethylhexane
    2,2-Dimethylhexane
    2,3-Dimethylhexane
    2,4-Dimethylhexane
    2,5-Dimethylhexane
    3,3-Dimethylhexane
    3,4-Dimethylhexane (meso compound)
    3-Ethyl-2-methylpentane
    3-Ethyl-3-methylpentane
    2,2,3-Trimethylpentane
    2,2,4-Trimethylpentane (isooctane)
    2,3,3-Trimethylpentane
    2,3,4-Trimethylpentane
    2,2,3,3-Tetramethylbutane
All of these, and many others, can be components of the gasoline we use to
fuel our vehicles. Why you think otherwise is problematic. Do you have any
background in refining? Benzene is no longer used as a motor fuel because it
is so carcinogenic. Obviously, octane and octane number are two different
animals. Forgive my assumption that you were sophisticated enough to draw
this conclusion from my post. My bad. Also, kerosene does not have a high
octane number. If you had spent some time with a knock engine you would know
this. My research tells me kerosene has an octane number of "between 15 and
25". Finally, your amused ignorance is becoming so very tiresome. You might
want to think about picking-on someone who shares your limited intellectual
prowess.
"It is better to remain silent and be thought a fool than to open one's
mouth and remove all doubt. (Voltaire)"
Grumpy AuContraire - 26 Jun 2009 03:45 GMT
> Okay, this was way back.  Like when we were driving an almost brand
> new 84 Escort GT.  There was a gas station on I35 in Farmer's Branch
> (just north of Dallas) that sold various "high premium" fuels.  One of
> them as 112 octane "uncracked".  Just what does that mean?

All I can say that "cracking" is part of the refining process where
individual hydrocarbon types are separated by specific temperature
ranges.  What it means in your reference is a mystery to me though..

> I'm "old enough" to have put Sunoco 120 in my 427 Galaxie 500.  Um,
> when I was doing the quarter, it kind of needed it.

Weren't all Sunoco blends in the 200 range?  Seems to me that My old
Studebaker Avanti would barely tolerate "260" which IIRC was the highest
available blend.

JT
Jim Yanik - 26 Jun 2009 13:38 GMT
>> Okay, this was way back.  Like when we were driving an almost brand
>> new 84 Escort GT.  There was a gas station on I35 in Farmer's Branch
[quoted text clipped - 13 lines]
>
> JT

260 is what I recall.

Signature

Jim Yanik
jyanik
at
kua.net

News - 26 Jun 2009 13:52 GMT
>>> Okay, this was way back.  Like when we were driving an almost brand
>>> new 84 Escort GT.  There was a gas station on I35 in Farmer's Branch
[quoted text clipped - 14 lines]
>
> 260 is what I recall.

It was Sunoco "Blue" 260.  Top of the commercial line.

The only thing better was the 115/145 purple avgas down at the air base.
Dh - 26 Jun 2009 22:37 GMT
>>>> Okay, this was way back.  Like when we were driving an almost brand
>>>> new 84 Escort GT.  There was a gas station on I35 in Farmer's Branch
[quoted text clipped - 18 lines]
>
> The only thing better was the 115/145 purple avgas down at the air base.

Another purple pump.
http://news.google.com/newspapers?nid=953&dat=19580428&id=La4LAAAAIBAJ&sjid=YlUD
AAAAIBAJ&pg=2455,4372763

drag image around as in google earth

http://www.goantiques.com/scripts/images,id,1943645.html
jim beam - 27 Jun 2009 03:06 GMT
>> Okay, this was way back.  Like when we were driving an almost brand
>> new 84 Escort GT.  There was a gas station on I35 in Farmer's Branch
[quoted text clipped - 4 lines]
> individual hydrocarbon types are separated by specific temperature
> ranges.  What it means in your reference is a mystery to me though..

separation by temperature is called "distillation".  "cracking" is
either extreme heat [inefficient] or catalysis.

>> I'm "old enough" to have put Sunoco 120 in my 427 Galaxie 500.  Um,
>> when I was doing the quarter, it kind of needed it.
[quoted text clipped - 4 lines]
>
> JT
 
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