Higher Octane fuel does not burn "more rapidly". Octane is
derived from the mix of fuels blended at the refinery after
cracking. Some of the combustibles you get from refining are;
methane, propane and butane. All three of them are hydrocarbons.
Methane has just a single carbon atom. Propane has three carbon
atoms chained together. Butane has four carbon atoms chained
together. Pentane has five, hexane has six, heptane has seven
and octane has eight carbons chained together.
Heptane ignites at a lower temperature than octane. (For temperature,
read compression - the more compression, the higher the temp). Ideally,
you want a blend of heptane and octane that is right at the ignition
temp when the spark goes off. Eighty-seven-octane gasoline is gasoline
that contains 87-percent octane and 13-percent heptane (or some other
combination of fuels that has the same performance of the 87/13
combination of octane/heptane).
Sometime in the 1940s, it was discovered that cheap gas could be used
in high-compression engines by adding combustion INHIBITORS - like
tetra-ethyl lead. Combustion inhibitors definitely do NOT make the
fuel burn more rapidly. They (get ready for it) INHIBIT combustion.
While we've decided that spewing tons of lead into the environment
is a bad thing, we still use other chemicals to achieve the combustion
inhibiting effect that one gets for a given heptane/octane blend.
There are a couple of levels of pinging - one is indeed caused by
the proper and desired flame front compressing the remaining fuel-
air mixture in the combustion chamber. But another name for pinging
is pre-ignition. Under severe conditions, the mixture will actually
detonate _before_ the spark. Causes for this are either severely
underated octane in a high-compression engine, or an older engine
that has a good buildup of carbon crud, the rough edges of which
can serve as glowing hot spots to pre-ignite the fuel/air mix.
Symptoms of the latter can include dieseling, or run-on, where the
ignition is cut off, yet the engine continues to chug and puff on
with no spark. With the prevelance of electrically controlled
injection systems, dieseling is less heard of these days. Carbed
engines would deliver fuel/air as long as the engine was turning,
but injected engines stop the fuel when the ignition is cut off.
In general, use the lowest octane you can get away with. The myth
of Premium being somehow faster-burning when to make higher-octane
fuels combustion inhibitors are typically added is still a prevalant
piece of internal combustion folklore.
Conrad
P.S. Be nice to our air - av-gas still contains lead - use it if
you gotta fly somewhere - not drive to burger king.
> Actually higher octane fuel does not ignite at a higher temperature, it
> simply burns more rapidly. Here's how pre-ignition happens. With lower
[quoted text clipped - 25 lines]
> though.
> Good luck!
Ernie Sparks - 03 Apr 2005 06:55 GMT
The (Nutter) plates in the cracking towers pull off different types of
distillants at different heights (temps). We're not talking about gasses
here but rather direct petro products.
In fact higher octane fuels (with additives) do support a faster moving
flame front. I simply refer to this as a "more rapid" burn, or burn rate.
The KISS process is more practical when trying to explain what takes place
in these instances.
The fact is the description is accurate. Pre-ignition is normally referred
to as dieseling and gasoline engines will do this if the temp inside the
cylinder is hot enough and something hanging around in the chamber is hot
(glowing, usually) enough to keep the ole pistons moving. Nuff said on this
thread.
Rodney T. Grill - 06 Apr 2005 14:33 GMT
> Heptane ignites at a lower temperature than octane. (For temperature,
> read compression - the more compression, the higher the temp).
[quoted text clipped - 3 lines]
> (or some other combination of fuels that has the same performance of
> the 87/13 combination of octane/heptane).
Modern refined gasoline generally contains between 70% and 90% isooctane
(and is usually on the lower side). The octane *rating* posted on the pump
only indicates the fuel's performance as compared to fuel with this
percentage of isooctane. This means a fuel with an 89 octane rating might
only be 75% isooctane, but it has enough anti-knock compounds added so that
it performs as if it were 89% isooctane. This performance is proven in test
engines. By the way, octane ratings are linear, so you could use half a
tank of 89 and half a tank of 93 and be running 91 octane. In fact, some
gas stations only store two tanks of fuel (their highest rating and their
lowest rating) and then combine them at the pump to get the "middle" grade.

Signature
- RODNEY
Ernie Sparks - 07 Apr 2005 02:19 GMT
Good info. Thanks for the reply.